Spontaneous resolution upon crystallization of allenyl-bis-phosphine oxides.
نویسندگان
چکیده
The first example of 'spontaneous resolution by crystallization' in allene chemistry, by means of crystal structures and solid state CD spectra of the R and S enantiomers, is presented. These allenes are prepared by the simple reaction of Ph2PCl with o-nitro functionalized propargyl alcohols.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 51 33 شماره
صفحات -
تاریخ انتشار 2015